朱钢国

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朱钢国的个人简介朱钢国，男，2008年12月－今：浙江师范大学化学系任教。现为教授、硕士生导师、化学与生命科学学院副院长，2009年入选浙江� �151”人才第三层次培养对象，2013年入选省高校中

朱钢国的个人简介

朱钢国，男，2008年12月－今：浙江师范大学化学系任教。现为教授、硕士生导师、化学与生命科学学院副院长，2009年入选浙江省“151”人才第三层次培养对象，2013年入选省高校中青年学科带头人。目前已发表Org. Lett.、Chem. Commun.、Chem. Eur. J.、Adv. Synth. Catal.、J. Org. Chem.等SCI论文45篇，其中，影响因子大于4有31篇，SCI引用700余次，研究结果多次被有机化学热点评论专栏(Org. Chem. Highlights)作为亮点工作之一进行评述，主要从事过渡金属催化的新反应研究和生理活性的天然产物全合成。

个人简介

朱钢国，男，1978年10月生，浙江省金华市金东区人，现为浙江师范大学化学与生命科学学院教授、硕士生导师

学习经历

1996.9-2000.7浙江师范大学化学系获理学学士，化学专业

2000.9-2005.7 中科院上海有机化学研究所获理学博士，有机化学专业

2005.9-2007.10美国普渡大学诺贝尔奖得主Negishi小组博士后研究

2007.11-2008.10 美国印第安纳大学化学系博士后研究

工作简历

2008.12-至今浙江师范大学化学与生命科学学院任教，教授（2011.12）

人才荣誉

浙江省“151”人才第三层次培养对象（2009.6）

浙江省高校中青年学科带头人(2013.6)

研究领域及成果

主要从事金属有机化学专业领域的研究，发表Chem. Commun.、Org. Lett.、Chem. Eur. J.、Adv. Synth. Catal.、J. Org. Chem.等SCI论文30多篇，著作章节1篇，其中以通讯作者或第一作者发表影响因子大于4论文19篇。

代表论著

1. Pd-catalyzed addition of boronic acids to ynol ethers: a highly regio- and stereoselective synthesis of trisubstituted vinyl ethers. Bai, Y.; Yin, J.; Kong, W.; Mao, M.; Zhu, G.* Chem. Commun.

2. A Regio- and Stereoselective Entry to ,-Disubstituted Vinyl Ethers via the Sequential Hydroboration/Suzukiu2013Miyaura Coupling of Ynol Ethers. Cui, W.; Mao, M.; He, Z.; Zhu, G.* J. Org. Chem.

3. Palladium-Catalyzed Direct Alkenylation of 2-Oxazolones: An Entry to 3,4,5-Trisubstituted 2-Oxazolones, Lu, Z.; Luo, F.; Wang, L.; Zhu, G.* J. Org. Chem.

4. Highly stereoselective synthesis of (Z)-1,2-dihaloalkenes by a Pd-catalyzed hydrohalogenation of alkynyl halides. Zhu, G.*; Chen, D.; Wang, Y.; Zheng, R. Chem. Commun.

5. Preparation of 3,4,5-Trisubstituted Oxazolones by Pd-Catalyzed Coupling of N-Alkynyl tert-Butyloxycarbamates with Aryl Halides and Related Electrophiles. Lu, Z.; Cui, W.; Xia, S.; Bai, Y.; Luo, F.; Zhu, G.* J. Org. Chem.

6. Palladium-catalyzed haloallylation of aromatic ynol ethers with allyl chlorides: a highly regio- and stereoselective approach to (1E)--chloroenol ethers. Cai, H.; Yuan, Z.; Zhu, W.; Zhu, G.* Chem. Commun.

7. Palladium-catalyzed highly regio- and stereoselective synthesis of (1E)- or (1Z)-1,2-dihalo-1,4-dienes via haloallylation of alkynyl halides. Chen, X.; Kong, W.; Cai, H.; Kong, L.; Zhu, G.* Chem. Commun.

8. Palladium-Catalyzed Dienylation of Haloalkynes Using 2,3-Butadienyl Acetates: A Facile Access to (1Z)-1,2-Dihalo-3-vinyl-1,3-dienes. Chen, D.; Chen, X.; Lu, Z.; Cai, H.; Shen, J.; Zhu, G.* Adv. Synth. Catal

9. Synthesis of Multisubstituted Enamides via Pd-Catalyzed Chloroallylation of Ynamides. Lu, Z.; Kong, W.; Yuan, Z.; Zhao, X.; Zhu. G.* J. Org. Chem

10. Palladium-Catalyzed Coupling of Haloalkynes with Allyl Acetate: A Highly Regio- and Stereoselective Synthesis of (Z)--Haloenol Acetates. Chen, X.; Chen, D.; Lu, Z.; Kong, L.; Zhu, G.* J. Org. Chem

11.Palladium-Catalyzed Hydroarylation, Hydroalkenylation, and Hydrobenzylation of Ynol Ethers with Organohalides: A Regio- and Stereoselective Entry toα,β- andβ,β-Disubstituted Alkenyl Ethers, Cui, W.; Ying, J.;Zheng, R.; Cheng, C.; Bai, Y.Zhu, G.*J. Org. Chem.2014,79, 3487-3493.

12.An unprecedented Pd-catalyzedtrans-addition of boronic acids to ynamides. Yang, Y.; Wang, L.; Zhang, J.; Jin, Y.;Zhu, G.*Chem. Commun.2014,50, 2347-2349.

13.Synthesis ofcis-1,2-dichlorovinylsulfones via Fe-catalyzed regio- and stereoselective addition of sulfonyl chlorides to aromatic chloroalkynes. Wang, L.; Zhu, H.; Che, J.; Yang, Y.*;Zhu, G.*Tetrahedron Lett.2014,55,1011-1013.

14.Synthesis of (Z)-1-Thio- and (Z)-2-Thio-1-alkenyl Boronates via Copper-Catalyzed Regiodivergent Hydroboration of Thioacetylenes: An Experimental and Theoretical Study.Zhu, G.*; Kong, W.; Feng, H.; Qian, Z.*J. Org. Chem.2014,79, 1786-1795.

15.A regio- and stereoselective entry to (Z)-β-halo alkenyl sulfides and their applications to the access of stereodefined trisubstituted alkenes. Liu, G.; Kong, L.; Shen, J.;Zhu, G.*Org. Biomol. Chem.2014,12, 2310-2321.

2013年

16.Palladium-Catalyzed Direct Alkenylation of 2-Oxazolones: An Entry to 3,4,5-Trisubstituted 2-Oxazolones, Lu, Z.; Luo, F.; Wang, L.;Zhu, G.*J. Org. Chem.2013,78, 10894-10901.

17.Pd-catalyzed addition of boronic acids to ynol ethers: a highly regio- and stereoselective synthesis of trisubstituted vinyl ethers. Bai, Y.; Yin, J.; Kong, W.; Mao, M.;Zhu, G.*Chem. Commun.2013,49,7650-7652.

18.Regioselective and Stereoselective Entry to β,β-Disubstituted Vinyl Ethers via the Sequential Hydroboration/Suzukiu2013Miyaura Coupling of Ynol Ethers. Cui, W.; Mao, M.; He, Z.;Zhu, G.*J. Org. Chem.2013,78, 9815-9821.

19.Copper-catalyzed direct thiolation of xanthines and related heterocycles with disulfides. He, Z.; Luo, F.;*Li, Y.;Zhu, G.*Tetrahedron Lett.2013,54, 5907-5910.

20.An operationally simple approach to (E)-α-halo vinyl sulfides and their applications for accessing stereodefined trisubstituted alkenes.Yang, Z.(本科生); Chen, X.; Kong, W.; Xia, S.; Zheng, R.; Luo, F.;Zhu, G.*Org. Biomol. Chem.2013,11, 2175-2185.

2012年

21.Highly stereoselective synthesis of (Z)-1,2-dihaloalkenesby a Pd-catalyzed hydrohalogenation of alkynyl halides.Zhu, G.*;Chen, D.; Wang, Y.; Zheng, R.Chem. Commun.2012,48,5796-5798.

22.Preparation of 3,4,5-Trisubstituted Oxazolones by Pd-Catalyzed Coupling ofN-Alkynyltert-Butyloxycarbamates with Aryl Halides and Related Electrophiles. Lu, Z.; Cui, W.; Xia, S.; Bai, Y.; Luo, F.;Zhu, G.*J. Org. Chem.2012,77,9871-9877.

23.A Facile Access to 3,5-Disubstituted Oxazolones Featuring a Cu-catalyzed Cyclization ofN-Alkynyltert-Butyl Carbamates. Lu, Z.; Yang, Z.; Cui, W.;Zhu, G.*Chem. Lett.2012,41, 636-638.

24.Approach to highly functionalized oxazolones by a Pd-catalyzed cyclization ofN-alkynyltert-butyloxycarbamates. Lu, Z.; Xu, X.; Yang, Z.; Kong, L.*;Zhu, G.*Tetrahedron Lett.2012,53,3433-3436.

25.A Facile Method for the Synthesis of 3-Alkyloxindole. Du, T.;Zhu, G.*; Zhou, J.*Lett. Org. Chem.2012,9, 225-232.